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    Bundling in brushes of directed and semiflexible polymers

    Panayotis Benetatos1,*, Eugene M. Terentjev2, and Annette Zippelius3,4

    • 1Department of Physics, Kyungpook National University, 80 Daehakro, Bukgu, Daegu 702-701, Korea
    • 2Cavendish Laboratory, University of Cambridge, 19 J.J. Thomson Avenue, Cambridge, CB3 0HE, United Kingdom
    • 3Institute for Theoretical Physics, Georg-August-Universität Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen, Germany
    • 4Max Planck Institute for Dynamics & Self-Organization, Am Fassberg 17, 37077 Göttingen, Germany

    • *pben@knu.ac.kr

    Phys. Rev. E 88, 042601 – Published 4 October, 2013

    DOI: https://doi.org/10.1103/PhysRevE.88.042601

    Abstract

    We explore the effect of an attractive interaction between parallel-aligned polymers which are perpendicularly grafted on a substrate. Such an attractive interaction could be due to, e.g., reversible cross-links. The competition between permanent grafting favoring a homogeneous state of the polymer brush and the attraction, which tends to induce in-plane collapse of the aligned polymers, gives rise to an instability of the homogeneous phase to a bundled state. In this latter state the in-plane translational symmetry is spontaneously broken and the density is modulated with a finite wavelength, which is set by the length scale of transverse fluctuations of the grafted polymers. We analyze the instability for two models of aligned polymers: directed polymers with line tension ε and weakly bending chains with bending stiffness κ.

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